Self-templated synthesis of uniform hollow spheres based on highly conjugated three-dimensional covalent organic frameworks.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 33144580.
- Also identified by DOI 10.1038/s41467-020-18844-4 and PMC identifier 7642269.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
Covalent organic frameworks (COFs) have served as a family of porous crystalline molecules for various promising applications. However, controllable synthesis of COFs with uniform morphology is paramount yet still remains quite challenging. Herein, we report self-templated synthesis of uniform and unique hollow spheres based on highly conjugated three-dimensional (3D) COFs with diameters of 500-700 nm. A detailed time-dependent study reveals the continuous transformation from initial nano sphere-like particles into uniform hollow spherical structures with Ostwald ripening mechanism. Particularly, the resulting 3D COF (3D-Sp-COF) is prone to transport ions more efficiently and the lithium-ion transference number (t<sup>+</sup>) of 3D-Sp-COF reaches 0.7, which even overwhelms most typical PEO-based polymer electrolytes. Inspiringly, the hollow spherical structures show enhanced capacitance performance with a specific capacitance of 251 F g<sup>-1</sup> at 0.5 A g<sup>-1</sup>, which compares favorably with the vast majority of two-dimensional COFs and other porous electrode materials.