High-pressure behavior of dielectric constant in a binary critical mixture.

Abstract

An alternative design of the measurement capacitor for high-pressure studies of complex liquids or soft matter systems is presented. Subsequently, results for the precritical anomaly of dielectric constant in 1-nitropropane-octane critical mixture are reported. First, the pressure dependence of the critical consolute temperature T_{C} up to P=0.55GPa was determined and portrayed using the derivative-based analysis. Second, temperature and pressure evolutions of dielectric constant on approaching the critical consolute point at (T_{C}=304.1K and P_{C}=403MPa) were studied. They revealed that the pretransitional anomaly ɛ(P→P_{C}) is notably more pronounced than for ɛ(T→T_{C}). For both paths, the static domain extends even to as low frequency as f=100Hz, whereas for tests under atmospheric pressure, they require at least f=100kHz. The discussion of the impact of correction-to-scaling terms, including the unique case of the pressure paths, is also presented.