Selective Ethanol Oxidation Reaction at the Rh-SnO₂ Interface.

Abstract

Direct ethanol fuel cells (DEFCs) are regarded as an attractive power source with high energy density, bio-renewability, and convenient storage and transportation. However, the anodic reaction of DEFCs, that is, the ethanol oxidation reaction (EOR), suffers from poor efficiency due to the low selectivity to CO₂ (C1 pathway) and high selectivity to CH₃ COOH (C2 pathway). In this study, the selective EOR to CO₂ can be achieved at the Rh-SnO₂ interface in SnO₂ -Rh nanosheets (NSs). The optimized catalyst of 0.2SnO₂ -Rh NSs/C exhibits excellent alkaline EOR performance with a mass activity of 213.2 mA mg_Rh ^-1 and a Faraday efficiency of 72.8% for the C1 pathway, which are 1.7 and 1.9 times higher than those of Rh NSs/C. Mechanism studies indicate that the strong synergy at the Rh-SnO₂ interface significantly promotes the breaking of CC bond of C₂ H₅ OH to form CO₂ , and facilitates oxidation of the poisonous intermediates (^* CO and ^* CH₃ ) to suppress the deactivation of the catalyst. This work not only provides a highly selective, active, and stable catalyst for the EOR, but also promotes fundamental research for the design of efficient catalysts via interface modification.