Fabrication of hydrophobic NiFe<sub>2</sub>O<sub>4</sub>@poly(DVB-LMA) sponge <i>via</i> a Pickering emulsion template method for oil/water separation.

Zhao, Caimei; Chen, Lei; Yu, Chuanming; Hu, Binghua; Huang, Haoxuan; Chen, Yongjie; Wang, Xin; Ye, Yongshi et al. · Soft Matter · 2021

basic_science · Level V

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Abstract

Super-hydrophobic porous absorbents are convenient, low-cost, efficient and environment-friendly materials in the treatment of oil spills. In this work, a simple Pickering emulsion template method was employed to fabricate an interconnected porous poly(DVB-LMA) sponge. A new co-Pickering stabilization system of Span 80 and NiFe2O4 nanoparticles was used to prepare ultra-concentrated internal phase water-in-oil (W/O) emulsions. After further polymerization, the resulting sponges were generated, which exhibited excellent adsorption selectivity due to the super-hydrophobicity and super-lipophilicity. Furthermore, the characterization results indicated that the composites had superior thermal stability, low density, high porosity and a flexible three-dimensional porous structure. Besides, the addition of nickel ferrite nanoparticles provided the materials with extra magnetic operability. High oil adsorption capacity (up to 36.9-84.2 g g-1), high oil retention, fast adsorption rate and superior reusability allowed the materials to be applied in the treatment of oily water.