Intermediate-Adduct-Assisted Growth of Stable CsPbI<sub>2</sub> Br Inorganic Perovskite Films for High-Efficiency Semitransparent Solar Cells.
basic_science · Level V
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- Record sourced from PubMed, PMID 33538006.
- Also identified by DOI 10.1002/adma.202006745.
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Abstract
Thanks to the tunable bandgap and excellent photoelectric characteristics, perovskites have been widely used in semitransparent solar cells (ST-SCs). Most works present unsatisfactory power conversion efficiencies (PCEs) through reducing the thickness of the perovskite films because there is a trade-off between PCE and average visible transmittance (AVT). As a consequence, most PCEs are less than 12% when the AVT is higher than 20% due to the limited voltage (V<sub>oc</sub> ) and short-circuit current (J<sub>sc</sub> ). Herein, a strategy of intermediate adduct (IMAT) engineering is developed to improve the film quality of the inorganic perovskite CsPbI<sub>2</sub> Br, which is a challenging issue to limit its performance of efficiency and stability. A normal n-i-p-structured PSC based on the optimal CsPbI<sub>2</sub> Br film delivers a PCE of 16.02% with excellent stability. Furthermore, through optimizing the electrode type and interface, the ST-PSC shows a high V<sub>oc</sub> larger than 1.2 V and the PCE reaches 14.01% and 10.36% under an AVT of 31.7% and 40.9%, respectively. This is the first demonstration of a CsPbI<sub>2</sub> Br ST-PSC, and it outperforms most of other types of perovskites.