Magnetic crystalline-symmetry-protected axion electrodynamics and field-tunable unpinned Dirac cones in EuIn<sub>2</sub>As<sub>2</sub>.

Riberolles, S X M; Trevisan, T V; Kuthanazhi, B; Heitmann, T W; Ye, F; Johnston, D C; Bud'ko, S L; Ryan, D H et al. · Nat Commun · 2021

basic_science · Level V

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Abstract

Knowledge of magnetic symmetry is vital for exploiting nontrivial surface states of magnetic topological materials. EuIn<sub>2</sub>As<sub>2</sub> is an excellent example, as it is predicted to have collinear antiferromagnetic order where the magnetic moment direction determines either a topological-crystalline-insulator phase supporting axion electrodynamics or a higher-order-topological-insulator phase with chiral hinge states. Here, we use neutron diffraction, symmetry analysis, and density functional theory results to demonstrate that EuIn<sub>2</sub>As<sub>2</sub> actually exhibits low-symmetry helical antiferromagnetic order which makes it a stoichiometric magnetic topological-crystalline axion insulator protected by the combination of a 180<sup>∘</sup> rotation and time-reversal symmetries: [Formula: see text]. Surfaces protected by [Formula: see text] are expected to have an exotic gapless Dirac cone which is unpinned to specific crystal momenta. All other surfaces have gapped Dirac cones and exhibit half-integer quantum anomalous Hall conductivity. We predict that the direction of a modest applied magnetic field of μ<sub>0</sub>H ≈ 1 to 2 T can tune between gapless and gapped surface states.