Interfacial engineering of Bi<sub>2</sub>S<sub>3</sub>/Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene based on work function for rapid photo-excited bacteria-killing.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 33619276.
- Also identified by DOI 10.1038/s41467-021-21435-6 and PMC identifier 7900204.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
In view of increasing drug resistance, ecofriendly photoelectrical materials are promising alternatives to antibiotics. Here we design an interfacial Schottky junction of Bi<sub>2</sub>S<sub>3</sub>/Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> resulting from the contact potential difference between Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> and Bi<sub>2</sub>S<sub>3</sub>. The different work functions induce the formation of a local electrophilic/nucleophilic region. The self-driven charge transfer across the interface increases the local electron density on Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>. The formed Schottky barrier inhibits the backflow of electrons and boosts the charge transfer and separation. The photocatalytic activity of Bi<sub>2</sub>S<sub>3</sub>/Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> intensively improved the amount of reactive oxygen species under 808 nm near-infrared radiation. They kill 99.86% of Staphylococcus aureus and 99.92% of Escherichia coli with the assistance of hyperthermia within 10 min. We propose the theory of interfacial engineering based on work function and accordingly design the ecofriendly photoresponsive Schottky junction using two kinds of components with different work functions to effectively eradicate bacterial infection.
Medical subject headings
- Bismuth
- Light
- Microbial Viability
- Sulfides
- Titanium