Broken-Gap PtS₂/WSe₂ van der Waals Heterojunction with Ultrahigh Reverse Rectification and Fast Photoresponse.

Abstract

Broken-gap van der Waals (vdW) heterojunctions based on 2D materials are promising structures to fabricate high-speed switching and low-power multifunctional devices thanks to its charge transport <i>versus</i> quantum tunneling mechanism. However, the tunneling current is usually generated under both positive and negative bias voltage, resulting in small rectification and photocurrent on/off ratio. In this paper, we report a broken-gap vdW heterojunction PtS₂/WSe₂ with a bilateral accumulation region design and a big band offset by utilizing thick PtS₂ as an effective carrier-selective contact, which exhibits an ultrahigh reverser rectification ratio approaching 10⁸ and on/off ratio over 10⁸ at room temperature. We also find excellent photodetection properties in such a heterodiode with a large photocurrent on/off ratio over 10⁵ due to its ultralow forward current and a comparable photodetectivity of 3.8 × 10¹⁰ Jones. In addition, the response time of such a photodetector reaches 8 μs owing to the photoinduced tunneling mechanism and reduced interface trapping effect. The proposed heterojunction not only demonstrates the high-performance broken-gap heterodiode but also provides in-depth understanding of the tunneling mechanism in the development of future electronic and optoelectronic applications.