CO₂ reduction on pure Cu produces only H₂ after subsurface O is depleted: Theory and experiment.

Abstract

We elucidate the role of subsurface oxygen on the production of C₂ products from CO₂ reduction over Cu electrocatalysts using the newly developed grand canonical potential kinetics density functional theory method, which predicts that the rate of C₂ production on pure Cu with no O is ∼500 times slower than H₂ evolution. In contrast, starting with Cu₂O, the rate of C₂ production is >5,000 times faster than pure Cu(111) and comparable to H₂ production. To validate these predictions experimentally, we combined time-dependent product detection with multiple characterization techniques to show that ethylene production decreases substantially with time and that a sufficiently prolonged reaction time (up to 20 h) leads only to H₂ evolution with ethylene production ∼1,000 times slower, in agreement with theory. This result shows that maintaining substantial subsurface oxygen is essential for long-term C₂ production with Cu catalysts.