Halide perovskite memristors as flexible and reconfigurable physical unclonable functions.

John, Rohit Abraham; Shah, Nimesh; Vishwanath, Sujaya Kumar; Ng, Si En; Febriansyah, Benny; Jagadeeswararao, Metikoti; Chang, Chip-Hong; Basu, Arindam et al. · Nat Commun · 2021

basic_science · Level V

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Abstract

Physical Unclonable Functions (PUFs) address the inherent limitations of conventional hardware security solutions in edge-computing devices. Despite impressive demonstrations with silicon circuits and crossbars of oxide memristors, realizing efficient roots of trust for resource-constrained hardware remains a significant challenge. Hybrid organic electronic materials with a rich reservoir of exotic switching physics offer an attractive, inexpensive alternative to design efficient cryptographic hardware, but have not been investigated till date. Here, we report a breakthrough security primitive exploiting the switching physics of one dimensional halide perovskite memristors as excellent sources of entropy for secure key generation and device authentication. Measurements of a prototypical 1 kb propyl pyridinium lead iodide (PrPyr[PbI<sub>3</sub>]) weak memristor PUF with a differential write-back strategy reveals near ideal uniformity, uniqueness and reliability without additional area and power overheads. Cycle-to-cycle write variability enables reconfigurability, while in-memory computing empowers a strong recurrent PUF construction to thwart machine learning attacks.