Effective EMI shielding behaviour of thin graphene/PMMA nanolaminates in the THz range.

Pavlou, Christos; Pastore Carbone, Maria Giovanna; Manikas, Anastasios C; Trakakis, George; Koral, Can; Papari, Gianpaolo; Andreone, Antonello; Galiotis, Costas · Nat Commun · 2021

basic_science · Level V

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Abstract

The use of graphene in a form of discontinuous flakes in polymer composites limits the full exploitation of the unique properties of graphene, thus requiring high filler loadings for achieving- for example- satisfactory electrical and mechanical properties. Herein centimetre-scale CVD graphene/polymer nanolaminates have been produced by using an iterative 'lift-off/float-on' process and have been found to outperform, for the same graphene content, state-of-the-art flake-based graphene polymer composites in terms of mechanical reinforcement and electrical properties. Most importantly these thin laminate materials show a high electromagnetic interference (EMI) shielding effectiveness, reaching 60 dB for a small thickness of 33 μm, and an absolute EMI shielding effectiveness close to 3·10<sup>5</sup> dB cm<sup>2</sup> g<sup>-1</sup> which is amongst the highest values for synthetic, non-metallic materials produced to date.