Coexistence of Superconductivity and Nontrivial Band Topology in Monolayered Cobalt Pnictides on SrTiO₃.

Abstract

As an intrinsically layered material, FeSe has been extensively explored for potentially revealing the underlying mechanisms of high transition temperature (high-<i>T</i>_c) superconductivity and realizing topological superconductivity and Majorana zero modes. Here we use first-principles approaches to identify that the cobalt pnictides of CoX (X = As, Sb, Bi), none of which is a layered material in bulk form. Nevertheless, all can be stabilized as monolayered systems either in freestanding form or supported on the SrTiO₃(001) substrate. We further show that each of the cobalt pnictides may potentially harbor high-<i>T</i>_c superconductivity beyond the Cu- and Fe-based superconducting families, and the underlying mechanism is inherently tied to their isovalency nature with the FeSe monolayer. Most strikingly, each of the monolayered CoX's on SrTiO₃ is shown to be topologically nontrivial, and our findings provide promising new platforms for realizing topological superconductors in the two-dimensional limit.