Photo-Switchable Nanoripples in Ti<sub>3</sub>C<sub>2</sub><i>T</i><sub><i>x</i></sub> MXene.
basic_science · Level V
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- Record sourced from PubMed, PMID 34464530.
- Also identified by DOI 10.1021/acsnano.1c03635.
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Abstract
MXenes are two-dimensional materials with a rich set of chemical and electromagnetic properties, the latter including saturable absorption and intense surface plasmon resonances. To fully harness the functionality of MXenes for applications in optics, electronics, and sensing, it is important to understand the interaction of light with MXenes on atomic and femtosecond dimensions. Here, we use ultrafast electron diffraction and high-resolution electron microscopy to investigate the laser-induced structural dynamics of Ti<sub>3</sub>C<sub>2</sub><i>T</i><sub><i>x</i></sub> nanosheets. We find an exceptionally fast lattice response with an electron-phonon coupling time of 230 fs. Repetitive femtosecond laser excitation transforms Ti<sub>3</sub>C<sub>2</sub><i>T</i><sub><i>x</i></sub> through a structural transition into a metamaterial with deeply sub-wavelength nanoripples that are aligned with the laser polarization. By a further laser illumination, the material is reversibly photo-switchable between a flat and rippled morphology. The resulting nanostructured MXene metamaterial with directional nanoripples is expected to exhibit an anisotropic optical and electronic response as well as an enhanced chemical activity that can be switched on and off by light.