Design Principles of Sodium/Potassium Protection Layer for High-Power High-Energy Sodium/Potassium-Metal Batteries in Carbonate Electrolytes: a Case Study of Na₂ Te/K₂ Te.

Abstract

The sodium (potassium)-metal anodes combine low-cost, high theoretical capacity, and high energy density, demonstrating promising application in sodium (potassium)-metal batteries. However, the dendrites' growth on the surface of Na (K) has impeded their practical application. Herein, density functional theory (DFT) results predict Na₂ Te/K₂ Te is beneficial for Na⁺ /K⁺ transport and can effectively suppress the formation of the dendrites because of low Na⁺ /K⁺ migration energy barrier and ultrahigh Na⁺ /K⁺ diffusion coefficient of 3.7 × 10^-10 cm² s^-1 /1.6 × 10^-10 cm² s^-1 (300 K), respectively. Then a Na₂ Te protection layer is prepared by directly painting the nanosized Te powder onto the sodium-metal surface. The Na@Na₂ Te anode can last for 700 h in low-cost carbonate electrolytes (1 mA cm^-2 , 1 mAh cm^-2 ), and the corresponding Na₃ V₂ (PO₄ )₃ //Na@Na₂ Te full cell exhibits high energy density of 223 Wh kg^-1 at an unprecedented power density of 29687 W kg^-1 as well as an ultrahigh capacity retention of 93% after 3000 cycles at 20 C. Besides, the K@K₂ Te-based potassium-metal full battery also demonstrates high power density of 20 577 W kg^-1 with energy density of 154 Wh kg^-1 . This work opens up a new and promising avenue to stabilize sodium (potassium)-metal anodes with simple and low-cost interfacial layers.