Advances in Microwave Synthesis of Nanoporous Materials.

Abstract

Usually, porous materials are synthesized by using conventional electric heating, which can be energy- and time-consuming. Microwave heating is commonly used in many households to quickly heat food. Microwave ovens can also be used as powerful devices in the synthesis of various porous materials. The microwave-assisted synthesis offers a simple, fast, efficient, and economic way to obtain many of the advanced nanomaterials. This review summarizes the recent achievements in the microwave-assisted synthesis of diverse groups of nanoporous materials including silicas, carbons, metal-organic frameworks, and metal oxides. Microwave-assisted methods afford highly porous materials with high specific surface areas (SSAs), e.g., activated carbons with SSA ≈3100 m² g^-1 , metal-organic frameworks with SSA ≈4200 m² g^-1 , covalent organic frameworks with SSA ≈2900 m² g^-1 , and metal oxides with relatively small SSA ≈300 m² g^-1 . These methods are also successfully implemented for the preparation of ordered mesoporous silicas and carbons as well as spherically shaped nanomaterials. Most of the nanoporous materials obtained under microwave irradiation show potential applications in gas adsorption, water treatment, catalysis, energy storage, and drug delivery, among others.