Strongly Anisotropic Strain-Tunability of Excitons in Exfoliated ZrSe<sub>3</sub>.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 34599777.
- Also identified by DOI 10.1002/adma.202103571 and PMC identifier 11468225.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
The effect of uniaxial strain on the band structure of ZrSe<sub>3</sub> , a semiconducting material with a marked in-plane structural anisotropy, is studied. By using a modified three-point bending test apparatus, thin ZrSe<sub>3</sub> flakes are subjected to uniaxial strain along different crystalline orientations monitoring the effect of strain on their optical properties through micro-reflectance spectroscopy. The obtained spectra show excitonic features that blueshift upon uniaxial tension. This shift is strongly dependent on the direction along which the strain is being applied. When the flakes are strained along the b-axis, the exciton peak shifts at ≈60-95 meV %<sup>-1</sup> , while along the a-axis, the shift only reaches ≈0-15 meV %<sup>-1</sup> . Ab initio calculations are conducted to study the influence of uniaxial strain, applied along different crystal directions, on the band structure and reflectance spectra of ZrSe<sub>3</sub> , exhibiting a remarkable agreement with the experimental results.