Silica hairy nanoparticles: a promising material for self-assembling processes.

Abstract

"Hairy" nanoparticles (HNPs), <i>i.e.</i> inorganic NPs functionalized with polymer chains, are promising building blocks for the synthesis of advanced nanocomposite (NC) materials having several technological applications. Recent evidence shows that HNPs self-organize in a variety of anisotropic structures, resulting in an improvement of the functional properties of the materials, in which are embedded. In this paper, we propose a three-step colloidal synthesis of spherical SiO₂-HNPs, with controlled particle morphology and surface chemistry. In detail, the SiO₂ core, synthesized by a modified Stöber method, was first functionalized with a short-chain amino-silane, which acts as an anchor, and then covered by maleated polybutadiene (PB), a rubbery polymer having low glass transition temperature, rarely considered until now. An extensive investigation by a multi-technique analysis demonstrates that the synthesis of SiO₂-HNPs is simple, scalable, and potentially applicable to different kind of NPs and polymers. Morphological analysis shows the overall distribution of SiO₂-HNPs with a certain degree of spatial organization, suggesting that the polymer coating induces a modification of NP-NP interactions. The role of the surface PB brushes in influencing the special arrangement of SiO₂-HNPs was observed also in <i>cis</i>-1,4-polybutadiene (<i>cis</i>-PB), since the resulting NC exhibited the particle packing in "string-like" superstructures. This confirms the tendency of SiO₂-HNPs to self-assemble and create alternative structures in polymer NCs, which may impart them peculiar functional properties.