Insights into Redox Processes and Correlated Performance of Organic Carbonyl Electrode Materials in Rechargeable Batteries.

Abstract

Organic carbonyl electrode materials have shown great prospects for rechargeable batteries in view of their high capacity, flexible designability, and sustainable production. However, organic carbonyl electrode materials still suffer from unsatisfactory electrochemical performance, which is highly relevant to their redox processes. Herein, an in-depth understanding on redox processes and the correlated electrochemical performance of organic carbonyl electrode materials is provided. The redox processes discussed mainly involve molecular structure evolution (intermediates), crystal structure evolution (phase transition), and charge storage mechanisms. The properties of intermediates can affect voltage, cycling stability, reversible capacity, and rate performance of batteries. Moreover, the reversible capacity/cycling stability and rate performance would be also influenced by phase transition and charge storage mechanisms (diffusion- or surface-controlled), respectively. To accelerate the practical applications of organic carbonyl electrode materials, future work should focus on developing more in situ or operando characterization techniques and further understanding the intrinsic relationships between redox processes and performance. It is hoped that the work discussed herein will stimulate more attention to the detailed redox processes and their correlations with the performance of organic carbonyl electrode materials in rechargeable batteries.