Probing dark exciton navigation through a local strain landscape in a WSe<sub>2</sub> monolayer.

Gelly, Ryan J; Renaud, Dylan; Liao, Xing; Pingault, Benjamin; Bogdanovic, Stefan; Scuri, Giovanni; Watanabe, Kenji; Taniguchi, Takashi et al. · Nat Commun · 2022

basic_science · Level V

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Abstract

In WSe<sub>2</sub> monolayers, strain has been used to control the energy of excitons, induce funneling, and realize single-photon sources. Here, we developed a technique for probing the dynamics of free excitons in nanoscale strain landscapes in such monolayers. A nanosculpted tapered optical fiber is used to simultaneously generate strain and probe the near-field optical response of WSe<sub>2</sub> monolayers at 5 K. When the monolayer is pushed by the fiber, its lowest energy states shift by as much as 390 meV (>20% of the bandgap of a WSe<sub>2</sub> monolayer). Polarization and lifetime measurements of these red-shifting peaks indicate they originate from dark excitons. We conclude free dark excitons are funneled to high-strain regions during their long lifetime and are the principal participants in drift and diffusion at cryogenic temperatures. This insight supports proposals on the origin of single-photon sources in WSe<sub>2</sub> and demonstrates a route towards exciton traps for exciton condensation.