Inherent structure landscape of hard spheres confined to narrow cylindrical channels.

Abstract

The inherent structure landscape for a system of hard spheres confined to a hard cylindrical channel, such that spheres can only contact their first and second neighbors, is studied using an analytical model that extends previous results [Phys. Rev. Lett. 115, 025702 (2015)PRLTAO0031-900710.1103/PhysRevLett.115.025702] to provide a comprehensive picture of jammed packings over a range of packing densities. In the model, a packing is described as an arrangement of k helical sections, separated by defects, that have alternating helical twist directions and where all spheres satisfy local jamming constraints. The structure of each helical section is determined by a single helical twist angle, and a jammed packing is obtained by minimizing the length of the channel per particle with respect to the k helical section angles. An analysis of a small system of N=20 spheres shows that the basins on the inherent structure landscape associated with these helical arrangements split into a number of distinct jammed states separated by low barriers giving rise to a degree of hierarchical organization. The model accurately predicts the geometric properties of packings generated using the Lubachevsky and Stillinger compression scheme (N=10^{4}) and provides insight into the nature of the probability distribution of helical section lengths.