Inner core composition paradox revealed by sound velocities of Fe and Fe-Si alloy.

Huang, Haijun; Fan, Lili; Liu, Xun; Xu, Feng; Wu, Ye; Yang, Gang; Leng, Chunwei; Wang, Qingsong et al. · Nat Commun · 2022

basic_science · Level V

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Abstract

Knowledge of the sound velocity of core materials is essential to explain the observed anomalously low shear wave velocity (V<sub>S</sub>) and high Poisson's ratio (σ) in the solid inner core. To date, neither V<sub>S</sub> nor σ of Fe and Fe-Si alloy have been measured under core conditions. Here, we present V<sub>S</sub> and σ derived from direct measurements of the compressional wave velocity, bulk sound velocity, and density of Fe and Fe-8.6 wt%Si up to ~230 GPa and ~5400 K. The new data show that neither the effect of temperature nor incorporation of Si would be sufficient to explain the observed low V<sub>S</sub> and high σ of the inner core. A possible solution would add carbon (C) into the solid inner core that could further decrease V<sub>S</sub> and increase σ. However, the physical property-based Fe-Si-C core models seemingly conflict with the partitioning behavior of Si and C between liquid and solid Fe.