Comb-type polymer-hybridized MXene nanosheets dispersible in arbitrary polar, nonpolar, and ionic solvents.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 35353563.
- Also identified by DOI 10.1126/sciadv.abl5299 and PMC identifier 8967220.
- Licence recorded as CC BY-NC.
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Abstract
Solution-based processing of two-dimensional (2D) nanomaterials is highly desirable, especially for the low-temperature large-area fabrication of flexible multifunctional devices. MXenes, an emerging family of 2D materials composed of transition metal carbides, carbonitrides, or nitrides, provide excellent electrical and electrochemical properties through aqueous processing. Here, we further expand the horizon of MXene processing by introducing a polymeric superdispersant for MXene nanosheets. Segmented anchor-spacer structures of a comb-type polymer, polycarboxylate ether (PCE), provide polymer grafting-like steric spacings over the van der Waals range of MXene surfaces, thereby reducing the colloidal interactions by the order of 10<sup>3</sup>, regardless of solvent. An unprecedented broad dispersibility window for Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> MXene, covering polar, nonpolar, and even ionic solvents, was achieved. Furthermore, close PCE entanglements in MXene@PCE composite films resulted in highly robust properties upon prolonged mechanical and humidity stresses.