Electrically Suppressed Outflow of Confined Liquid in Hydrophobic Nanopores.

Abstract

Confining liquid in a hydrophobic nanoenvironment has enabled a broad spectrum of applications in biomedical sensors, mechanical actuators, and energy storage and converters, where the outflow of confined liquid is spontaneous and fast due to the intrinsic hydrophobic nature of nanopores with extremely low interfacial friction, challenging design capacity and control tolerance of structures and devices. Here, we present a facile approach of suppressing the outflow of water confined in hydrophobic nanopores with an electric field. Extensive molecular dynamics simulations show that the presence of an electric field could significantly strengthen hydrogen bonds and retard degradations of the associated networks during the outflow. The outflow deformation and strength are extracted to quantitatively characterize the electrical suppression to outflow and agree well with simulations. This study proposes a practical means of impeding the fast liquid outflow in hydrophobic nanopores, potentially useful for devising nanofluidics-based functional structures and devices with controllable performance.