2D Metal-Organic Framework Cu<sub>3</sub> (HHTT)<sub>2</sub> Films for Broadband Photodetectors from Ultraviolet to Mid-Infrared.
basic_science · Level V
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- Record sourced from PubMed, PMID 35765163.
- Also identified by DOI 10.1002/adma.202204140.
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Abstract
Cu<sub>3</sub> (HHTT)<sub>2</sub> (HHTT: 2,3,7,8,12,13-hexahydroxytetraazanaphthotetraphene) is a novel 2D conjugated metal-organic framework (2D c-MOF) with efficient in-plane d-π conjugations and strong interlayer π-π interactions while the growth of Cu<sub>3</sub> (HHTT)<sub>2</sub> thin films has never been reported until now. Here, the successful fabrication of highly oriented wafer-scale Cu<sub>3</sub> (HHTT)<sub>2</sub> thin films with a layer-by-layer growth method on various substrates is presented. Its semiconducting behavior and carrier transport mechanisms are clarified through temperature and frequency-dependent conductivity measurements. Flexible photodetectors based on Cu<sub>3</sub> (HHTT)<sub>2</sub> thin films exhibit reliable photoresponses at room temperature in a wavelength region from UV to mid-IR, which is much broader than those of solution-processed broadband photodetectors reported previously. Moreover, the photodetectors can show a typical synaptic behavior and excellent data recognition accuracy in artificial neural networks. This work opens a window for the exploration of high-performance and multifunctional optoelectronic devices based on 2D c-MOFs.