Efficient Eco-Friendly Flexible X-ray Detectors Based on Molecular Perovskite.

Abstract

Next-generation wearable electronics requires mechanical robustness. In addition to the previously reported eco-friendliness, low cost, and light weight of molecular perovskites, flexibility is also a desired merit for their practical use. Here we design a flexible X-ray detector based on a novel molecular perovskite, DABCO-CsBr₃ (DABCO = <i>N</i>-<i>N</i>'-diazabicyclo[2.2.2]octonium), which is the missing link between metal-free molecular perovskites A(NH₄)X₃ (A = divalent organic ammoniums) and conventional metal halide based ABX₃ (B = divalent metal cations) perovskites. DABCO-CsBr₃ inherits its band nature from A(NH₄)X₃, while it exhibits a stronger stopping power. DABCO-CsBr₃ shows potential for high-performance ionizing radiation detectors due to low dark current, low ion migration, and an efficient mobility-lifetime (μτ) product. Finally, a molecular-perovskite-based flexible X-ray detector is demonstrated on the basis of the DABCO-CsBr₃/poly(vinylidene fluoride) composite, with a sensitivity of 106.7 μC Gy_air^-1 cm^-2. This work enriches the molecular perovskite family and highlights the promise of molecular perovskites for the next-generation eco-friendly and wearable optoelectronic devices.