Virial coefficients of hard hyperspherocylinders in R^{4}: Influence of the aspect ratio.
basic_science · Level V
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- Record sourced from PubMed, PMID 35854598.
- Also identified by DOI 10.1103/PhysRevE.105.064121.
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Abstract
We provide second- to sixth-order virial coefficients of hard hyperspherocylinders in dependence on their aspect ratio ν. Virial coefficients of an anisotropic geometry in four dimensions are calculated employing an optimized Mayer-sampling algorithm. As the second virial coefficient of a hard particle is identical to its excluded hypervolume, the numerically obtained second virial coefficients can be compared to analytical relations for the excluded hypervolume based on geometric measures of the respective, convex geometry in dependence on its aspect ratio ν.