Electron Microscopy Probing Electron-Photon Interactions in SiC Nanowires with Ultrawide Energy and Momentum Match.

Du, Jinlong; Chen, Jin-Hui; Li, Yuehui; Shi, Ruochen; Wu, Mei; Xiao, Yun-Feng; Gao, Peng · Nano Lett · 2022

basic_science · Level V

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Abstract

Light-matter interactions are commonly probed by optical spectroscopy, which, however, has some fundamental limitations such as diffraction-limited spatial resolution, tiny momentum transfer, and noncontinuous excitation/detection. In this work, through the use of scanning transmission electron microscopy-electron energy loss spectroscopy (STEM-EELS) with ultrawide energy and momentum match and subnanometer spatial resolution, the longitudinal Fabry-Perot (FP) resonating modes and the transverse whispering-gallery modes (WGMs) in individual SiC nanowires are simultaneously excited and detected, which span from near-infrared (∼1.2 μm) to ultraviolet (∼0.2 μm) spectral regime, and the momentum transfer can range up to 10<sup>8</sup> cm<sup>-1</sup>. The size effects on the resonant spectra of nanowires are also revealed. This work provides an alternative technique to optical resonating spectroscopy and light-matter interactions in dielectric nanostructures, which is promising for modulating free electrons via photonic structures.