Three-dimensional printing of photonic colloidal glasses into objects with isotropic structural color.

Demirörs, Ahmet F; Poloni, Erik; Chiesa, Maddalena; Bargardi, Fabio L; Binelli, Marco R; Woigk, Wilhelm; de Castro, Lucas D C; Kleger, Nicole et al. · Nat Commun · 2022

basic_science · Level V

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Abstract

Structural color is frequently exploited by living organisms for biological functions and has also been translated into synthetic materials as a more durable and less hazardous alternative to conventional pigments. Additive manufacturing approaches were recently exploited for the fabrication of exquisite photonic objects, but the angle-dependence observed limits a broader application of structural color in synthetic systems. Here, we propose a manufacturing platform for the 3D printing of complex-shaped objects that display isotropic structural color generated from photonic colloidal glasses. Structurally colored objects are printed from aqueous colloidal inks containing monodisperse silica particles, carbon black, and a gel-forming copolymer. Rheology and Small-Angle-X-Ray-Scattering measurements are performed to identify the processing conditions leading to printed objects with tunable structural colors. Multimaterial printing is eventually used to create complex-shaped objects with multiple structural colors using silica and carbon as abundant and sustainable building blocks.