Determination of Crystallographic Orientation and Exposed Facets of Titanium Oxide Nanocrystals.
basic_science · Level V
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- Record sourced from PubMed, PMID 35916758.
- Also identified by DOI 10.1002/adma.202203320.
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Abstract
Titanium dioxide (TiO<sub>2</sub> ) nanocrystals have attracted great attention in heterogeneous photocatalysis and photoelectricity fields for decades. However, contradicting conclusions on the crystallographic orientation and exposed facets of TiO<sub>2</sub> nanocrystals frequently appear in the literature. Herein, using anatase TiO<sub>2</sub> nanocrystals with highly exposed {001} facets as a model, the misleading conclusions that exist on anatase nanocrystals are clarified. Although TiO<sub>2</sub> -001 nanocrystals are recognized to be dominated by {001} facets, in fact, anatase nanocrystals with both dominant {001} and {111} facets always co-exist due to the similarities in the lattice fringes and intersection angles between the two types of facets (0.38 nm and 90° in the [001] direction, 0.35 nm and 82° in the [111] direction). A paradigm for determining the crystallographic orientation and exposed facets based on transmission electron microscopy (TEM) analysis, which provides a universal methodology to nanomaterials for determining the orientation and exposed facets, is also given.