Ultra-compact MXene fibers by continuous and controllable synergy of interfacial interactions and thermal drawing-induced stresses.

Zhou, Tianzhu; Yu, Yangzhe; He, Bing; Wang, Zhe; Xiong, Ting; Wang, Zhixun; Liu, Yanting; Xin, Jiwu et al. · Nat Commun · 2022

basic_science · Level V

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Abstract

Recent advances in MXene (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) fibers, prepared from electrically conductive and mechanically strong MXene nanosheets, address the increasing demand of emerging yet promising electrode materials for the development of textile-based devices and beyond. However, to reveal the full potential of MXene fibers, reaching a balance between electrical conductivity and mechanical property is still the fundamental challenge, mainly due to the difficulties to further compact the loose MXene nanosheets. In this work, we demonstrate a continuous and controllable route to fabricate ultra-compact MXene fibers with an in-situ generated protective layer via the synergy of interfacial interactions and thermal drawing-induced stresses. The resulting ultra-compact MXene fibers with high orientation and low porosity exhibit not only excellent tensile strength and ultra-high toughness, but also high electrical conductivity. Then, we construct meter-scale MXene textiles using these ultra-compact fibers to achieve high-performance electromagnetic interference shielding and personal thermal management, accompanied by the high mechanical durability and stability even after multiple washing cycles. The demonstrated generic strategy can be applied to a broad range of nanostructured materials to construct functional fibers for large-scale applications in both space and daily lives.