Flexible thermoelectrics based on ductile semiconductors.

Yang, Qingyu; Yang, Shiqi; Qiu, Pengfei; Peng, Liming; Wei, Tian-Ran; Zhang, Zhen; Shi, Xun; Chen, Lidong · Science · 2022

basic_science · Level V

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Abstract

Flexible thermoelectrics provide a different solution for developing portable and sustainable flexible power supplies. The discovery of silver sulfide-based ductile semiconductors has driven a shift in the potential for flexible thermoelectrics, but the lack of good p-type ductile thermoelectric materials has restricted the reality of fabricating conventional cross-plane π-shaped flexible devices. We report a series of high-performance p-type ductile thermoelectric materials based on the composition-performance phase diagram in AgCu(Se,S,Te) pseudoternary solid solutions, with high figure-of-merit values (0.45 at 300 kelvin and 0.68 at 340 kelvin) compared with other flexible thermoelectric materials. We further demonstrate thin and flexible π-shaped devices with a maximum normalized power density that reaches 30 μW cm<sup>-2</sup> K<sup>-2</sup>. This output is promising for the use of flexible thermoelectrics in wearable electronics.