Atomic-scale observation of dynamic grain boundary structural transformation during shear-mediated migration.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 36367931.
- Also identified by DOI 10.1126/sciadv.abn3785 and PMC identifier 9651741.
- Licence recorded as CC BY-NC.
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Abstract
Grain boundary (GB) structural change is commonly observed during and after stress-driven GB migration in nanocrystalline materials, but its exact atomic scale transformation has not been explored experimentally. Here, using in situ high-resolution transmission electron microscopy combined with molecular dynamics simulations, we observed the dynamic GB structural transformation stemming from reversible facet transformation and GB dissociation during the shear-mediated migration of faceted GBs in gold nanocrystals. A reversible transformation was found to occur between (002)/(111) and Σ11(113) GB facets, accomplished by the coalescence and detachment of [Formula: see text]-type GB steps or disconnections that mediated the GB migration. In comparison, the dissociation of (002)/(111) GB into Σ11(113) and Σ3(111) GBs occurred via the reaction of [Formula: see text]-type steps that involved the emission of partial dislocations. Furthermore, these transformations were loading dependent and could be accommodated by GB junctions. This work provides atomistic insights into the dynamic structural transformation during GB migration.