Toward economical application of carbon capture and utilization technology with near-zero carbon emission.

Abstract

Carbon capture and utilization technology has been studied for its practical ability to reduce CO₂ emissions and enable economical chemical production. The main challenge of this technology is that a large amount of thermal energy must be provided to supply high-purity CO₂ and purify the product. Herein, we propose a new concept called reaction swing absorption, which produces synthesis gas (syngas) with net-zero CO₂ emission through direct electrochemical CO₂ reduction in a newly proposed amine solution, triethylamine. Experimental investigations show high CO₂ absorption rates (>84%) of triethylamine from low CO₂ concentrated flue gas. In addition, the CO Faradaic efficiency in a triethylamine supplied membrane electrode assembly electrolyzer is approximately 30% (@-200 mA cm^-2), twice higher than those in conventional alkanolamine solvents. Based on the experimental results and rigorous process modeling, we reveal that reaction swing absorption produces high pressure syngas at a reasonable cost with negligible CO₂ emissions. This system provides a fundamental solution for the CO₂ crossover and low system stability of electrochemical CO₂ reduction.