Improving Relative Permittivity and Suppressing Dielectric Loss of Triboelectric Layers for High-Performance Wearable Electricity Generation.

Peng, Zehua; Xiao, Xiao; Song, Jianxin; Libanori, Alberto; Lee, Ching; Chen, Keda; Gao, Yuan; Fang, Yunsheng et al. · ACS Nano · 2022

basic_science · Level V

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Abstract

High relative permittivity and low dielectric loss are two desired parameters of a triboelectric layer to enhance its mechanical-to-electrical energy conversion efficiency in a triboelectric nanogenerator (TENG). However, the elevated permittivity of the triboelectric layer is always accompanied by increasing dielectric loss, limiting further improvement or even reducing the electrical output. Herein, we report a method for improving the relative permittivity and suppressing the dielectric loss of the triboelectric layer via nanoscale design at the particle-polymer interface. When incorporated with 2 wt % Ag@C, the triboelectric-layer-enhanced TENG (TLE-TENG) presents a 2.6-fold increment in relative permittivity and a 302% current enhancement. An instantaneous peak power density of 1.22 W m<sup>-2</sup>, an excellent pressure sensitivity of 90.95 V kPa<sup>-1</sup>, and an optimized sheet resistance (<i>∼</i>0.14 Ω/sq) are attributes of this greatly enhanced device. Such improvements bode well for the implementation of these enhancing strategies to help position TLE-TENGs as pervasive and sustainable power sources and active self-powered sensors in the era of the Internet of Things.