Diffusion-controlled annihilation A+B→0: Coalescence, fragmentation, and collapse of nonidentical A-particle islands submerged in the B-particle sea.

Abstract

We present a systematic analysis of diffusion-controlled interaction and collapse of two nonidentical spatially separated d-dimensional A-particle islands in the B-particle sea at propagation of the sharp reaction front A+B→0 at equal species diffusivities. We show that at a sufficiently large initial distance between the centers of islands 2ℓ and a relatively large initial ratio of island-to-sea concentrations, the evolution dynamics of the island-sea-island system demonstrates remarkable universality and, depending on the system dimension, is determined unambiguously by two dimensionless parameters Λ=N_{0}^{+}/N_{Ω} and q=N_{0}^{-}/N_{0}^{+}, where N_{0}^{+} and N_{0}^{-} are the initial particle numbers in the larger and smaller of the islands, respectively, and N_{Ω} is the initial number of sea particles in the volume Ω=(2ℓ)^{d}. We find that at each fixed 0<q≤1, there are threshold values Λ_{★}(q) and Λ_{s}(q)≥Λ_{★}(q) that depend on the dimension and separate the domains of individual death of each of the islands Λ<Λ_{★}(q), coalescence and subsequent fragmentation (division) of a two-centered island Λ_{★}(q)<Λ<Λ_{s}(q), and collapse of a single-centered island formed by coalescence Λ>Λ_{s}(q). We demonstrate that regardless of d, the trajectories of the island centers are determined unambiguously by the parameter q, and we reveal a detailed picture of the evolution of islands and front trajectories with an increase in Λ, focusing on the scaling laws of evolution at the final collapse stage and in the vicinity of starting coalescence and fragmentation points.