Semi-Transparent, Chiral Organic Photodiodes with Incident Direction-Dependent Selectivity for Circularly Polarized Light.
basic_science · Level V
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- Record sourced from PubMed, PMID 36577393.
- Also identified by DOI 10.1002/adma.202209730.
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Abstract
Detection of the circular polarization of light is possible using chiral semiconductors, yet the mechanisms remain poorly understood. Semi-transparent chiral photodiodes allow for a simple experiment to investigate the basis of their selectivity: changing the side from which the diode is illuminated. A reversal of circular selectivity is observed in photocurrent generation when changing the direction of illumination on organic, bulk-heterojunction cells. The change in selectivity can be explained by a space-charge limitation on the collection of photocarriers in combination with preferential absorption of one of the circular polarizations of near-infrared light by the chiral non-fullerene acceptor. The space-charge limitation is supported by detailed measurements of frequency and intensity dependence of dc and ac photocurrents.