Angell plot from the potential energy landscape perspective.

Abstract

Within the scenario of the potential energy landscape (PEL), a thermodynamic model has been developed to uncover the physics behind the Angell plot. In our model, by separating the barrier distribution in PELs into a Gaussian-like and a power-law form, we obtain a general relationship between the relaxation time and the temperature. The wide range of the experimental data in the Angell plot, as well as the molecular-dynamics data, can be excellently fitted by two characteristic parameters, the effective barrier (ω) and the effective width (σ) of a Gaussian-like distribution. More importantly, the fitted ω and σ^{2} for all glasses are found to have a simple linear relationship within a very narrow band, and fragile and strong glasses are well separated in the ω-σ^{2} plot, which indicates that glassy states appear only in a specific region of the PEL.