A Tunable Single-Molecule Light-Emitting Diode with Single-Photon Precision.

Yang, Chen; Guo, Yilin; Zhou, Shuyao; Liu, Zhirong; Liu, Zitong; Zhang, Deqing; Guo, Xuefeng · Adv Mater · 2023

basic_science · Level V

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Abstract

A robust single-molecule light-emitting diode (SM-LED) with high color purity, linear polarization, and efficiency tunability is prepared by covalently integrating one fluorescent molecule into nanogapped graphene electrodes. Furthermore, single-molecule Förster resonance energy transfer from the electroluminescent center to different accepters is achieved through rational molecular engineering, enabling construction of a multicolor SM-LED. All these characterizations are accomplished in the photoelectrical integration system with high temporal/spatial/energy resolution, demonstrating the capability of the single-photon emission of SM-LEDs. The success in developing high-performance SM-LEDs inspires the development of the next generation of commercial display devices and promises a single-photon emitter for use in quantum computation and quantum communication.