Nanostructured Materials for Photothermal Carbon Dioxide Hydrogenation: Regulating Solar Utilization and Catalytic Performance.

Abstract

Converting carbon dioxide (CO₂) into value-added fuels or chemicals through photothermal catalytic CO₂ hydrogenation is a promising approach to alleviate the energy shortage and global warming. Understanding the nanostructured material strategies in the photothermal catalytic CO₂ hydrogenation process is vital for designing photothermal devices and catalysts and maximizing the photothermal CO₂ hydrogenation performance. In this Perspective, we first describe several essential nanomaterial design concepts to enhance sunlight absorption and utilization in photothermal CO₂ hydrogenation. Subsequently, we review the latest progress in photothermal CO₂ hydrogenation into C₁ (e.g., CO, CH₄, and CH₃OH) and multicarbon hydrocarbon (C₂₊) products. Finally, the relevant challenges and opportunities in this exciting research realm are discussed. This perspective provides a comprehensive understanding for the light-heat synergy over nanomaterials and instruction for rational photothermal catalyst design for CO₂ utilization.