The Role of Surface and Interface Energy on Phase Stability of Nanosized Insertion Compounds.
basic_science · Level V
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- Record sourced from PubMed, PMID 36751057.
- Also identified by DOI 10.1002/adma.200803038.
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Abstract
Thermodynamic theory reveals the impact of surface and interface energies on the equilibrium properties and solubility limits of interstitial ions in nanosized crystallites. Applied to LixFePO<sub>4</sub> especially interface energy contributions play important roles, and their effect explains observations of the narrowing of electrochemically measured miscibility gaps in nanostructured electrodes.