Energy-Efficient Stable Hyperfluorescence Organic Light-Emitting Diodes with Improved Color Purities and Ultrahigh Power Efficiencies Based on Low-Polar Sensitizing Systems.
basic_science · Level V
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- Record sourced from PubMed, PMID 36893769.
- Also identified by DOI 10.1002/adma.202212237.
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Abstract
Multi-resonance (MR) molecules with thermally activated delayed fluorescence (TADF) are emerging as promising candidates for high-definition displays because of their narrow emission spectra. However, the electroluminescence (EL) efficiencies and spectra of MR-TADF molecules are highly sensitive to hosts and sensitizers when applied to organic light-emitting diodes (OLEDs), and the highly polar environments in devices often lead to significantly broadened EL spectra. In this study, a proof-of-concept TADF sensitizer (BTDMAC-XT) with low polarity, high steric hindrance, and concentration-quenching free feature is constructed, which acts as a good emitter in doped and non-doped OLEDs with high external quantum efficiencies (η<sub>ext</sub> s) of 26.7% and 29.3%, respectively. By combining BTDMAC-XT with conventional low-polarity hosts, low-polarity sensitizing systems with a small carrier injection barrier and full exciton utilization are constructed for the MR-TADF molecule BN2. Hyperfluorescence (HF) OLEDs employing the low-polar sensitizing systems successfully improve the color quality of BN2 and afford an excellent η<sub>ext</sub> of 34.4%, a record-high power efficiency of 166.3 lm W<sup>-1</sup> and a long operational lifetime (LT<sub>50</sub> = 40309 h) at an initial luminance of 100 cd m<sup>-2</sup> . These results provide instructive guidance for the sensitizer design and device optimization for energy-efficient and stable HF-OLEDs with high-quality light.