Accelerated inertial regime in the spinodal decomposition of magnetic fluids.

Singh, Anuj Kumar; Banerjee, Varsha · Soft Matter · 2023

basic_science · Level V

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Abstract

Furukawa predicted that at late times, the domain growth in binary fluids scales as (<i>t</i>) ∼ <i>t</i><sup>2/3</sup>, and the growth is driven by fluid inertia. The inertial growth regime has been highly elusive in molecular dynamics (MD) simulations. We perform coarsening studies of the (<i>d</i> = 3) Stockmayer (SM) model comprising of magnetic dipoles that interact <i>via</i> long-range dipolar interactions as well as the usual Lennard-Jones (LJ) potential. This fascinating polar fluid exhibits a gas-liquid phase coexistence, and magnetic order even in the absence of an external field. From comprehensive MD simulations, we observe the inertial scaling [(<i>t</i>) ∼ <i>t</i><sup>2/3</sup>] in the SM fluid for an extended time window. Intriguingly, the fluid inertia is overwhelming from the outset - our simulations do not show the early diffusive regime [(<i>t</i>) ∼ <i>t</i><sup>1/3</sup>] and the intermediate viscous regime [(<i>t</i>) ∼ <i>t</i>] prevalent in LJ fluids.