Porous Metal-Organic Framework/ReS<sub>2</sub> Heterojunction Phototransistor for Polarization-Sensitive Visual Adaptation Emulation.

Xie, Dingdong; Gao, Ge; Tian, Bobo; Shu, Zhiwen; Duan, Huigao; Zhao, Wei-Wei; He, Jun; Jiang, Jie · Adv Mater · 2023

basic_science · Level V

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Abstract

Visual adaptation allows organisms to accurately perceive the external world even in dramatically changing environments, from dim starlight to bright sunlight. In particular, polarization-sensitive visual adaptation can effectively process the polarized visual information that is ubiquitous in nature. However, such an intriguing characteristic still remains a great challenge in semiconductor devices. Herein, a novel porous metal-organic-framework phototransistor with anisotropic-ReS<sub>2</sub> -based heterojunction is demonstrated for polarization-sensitive visual adaptation emulation. The device exhibits intriguing polarized sensitivity and an adaptive ability due to its strong anisotropic and trapping-detrapping characteristics, respectively. A series of polarization-sensitive neuromorphic behaviors like polarization-perceptual excitatory postsynaptic current, multimode adjustable dichroic ratio and reconfigurable sensory adaption, are experimentally demonstrated through this porous heterojunction phototransistor. More importantly, with the polarization-electricity cooperation strategy, advanced polarization-sensitive visual adaptation with strong bottom-gate control and environment dependence is successfully realized. These results represent a significant step toward the new generation of intelligent visual perception systems in autonomous navigation and human-machine interaction, etc.