Cryo-EM structure of the endothelin-1-ET<sub>B</sub>-G<sub>i</sub> complex.

Sano, Fumiya K; Akasaka, Hiroaki; Shihoya, Wataru; Nureki, Osamu · Elife · 2023

basic_science · Level V

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Abstract

The endothelin ET<sub>B</sub> receptor is a promiscuous G-protein coupled receptor that is activated by vasoactive peptide endothelins. ET<sub>B</sub> signaling induces reactive astrocytes in the brain and vasorelaxation in vascular smooth muscle. Consequently, ET<sub>B</sub> agonists are expected to be drugs for neuroprotection and improved anti-tumor drug delivery. Here, we report the cryo-electron microscopy structure of the endothelin-1-ET<sub>B</sub>-G<sub>i</sub> complex at 2.8 Å resolution, with complex assembly stabilized by a newly established method. Comparisons with the inactive ET<sub>B</sub> receptor structures revealed how endothelin-1 activates the ET<sub>B</sub> receptor. The NPxxY motif, essential for G-protein activation, is not conserved in ET<sub>B</sub>, resulting in a unique structural change upon G-protein activation. Compared with other GPCR-G-protein complexes, ET<sub>B</sub> binds G<sub>i</sub> in the shallowest position, further expanding the diversity of G-protein binding modes. This structural information will facilitate the elucidation of G-protein activation and the rational design of ET<sub>B</sub> agonists.

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