Application of Conductive MOF in Zinc-Based Batteries.

Abstract

The use of conductive MOFs (c-MOFs) in zinc-based batteries has been a popular research direction. Zinc-based batteries are widely used with the advantages of high specific capacity and safety and stability, but they also face many problems. c-MOFs have excellent conductivity compared with other primitive MOFs, and therefore have better applications in zinc-based batteries. In this paper, the transfer mechanisms of the unique charges of c-MOFs: hop transport and band transport, respectively, are discussed and the way of electron transport is further addressed. Then, the various ways to prepare c-MOFs are introduced, among which solvothermal, interfacial synthesis, and postprocessing methods are widely used. In addition, the applications of c-MOFs are discussed in terms of their role and performance in different types of zinc-based batteries. Finally, the current problems of c-MOFs and the prospects for their future development are presented.