Two-Dimensional Sodium Channels with High Selectivity and Conductivity for Osmotic Power Generation from Wastewater.

Abstract

Conducting target ions rapidly while rejecting rival ions efficiently is challenging yet highly demanded for ion separation related applications. Two-dimensional (2D) channels are widely used for ion separation, but highly selective 2D channels generally suffer from a relatively low ionic conductivity. Here we report that the 2D vermiculite channels have a Na⁺ conductivity higher than bulk and at the same time reject heavy metal ions with a selectivity of a few hundreds. Such performance is attributed to the highly electronegative crystal surface and the extremely narrow channel (0.2 nm high), as also supported by the <i>ab initio</i> molecular dynamics simulation. We demonstrate that the highly selective and conductive sodium channels can be utilized to harvest osmotic power from industrial wastewater, achieving a power density of more than 20 W m^-2 while preventing pollution from waste heavy metal ions. This work provides a strategy for wastewater utilization as well as treatment. Moreover, the investigation suggests the possibility to break the ionic permeability-selectivity trade-off by combining Ångstrom-scale confinement with proper surface engineering, which could lead to applications that are challenging for previous materials.