Manipulating Electron Redistribution in Ni<sub>2</sub> P for Enhanced Alkaline Seawater Electrolysis.
basic_science · Level V
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- Record sourced from PubMed, PMID 37740701.
- Also identified by DOI 10.1002/adma.202307395.
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Abstract
Developing bifunctional electrocatalyst for seawater splitting remains a persistent challenge. Herein, an approach is proposed through density functional theory (DFT) preanalysis to manipulate electron redistribution in Ni<sub>2</sub> P addressed by cation doping and vacancy engineering. The needle-like Fe-doped Ni<sub>2</sub> P with P vacancy (Fe-Ni<sub>2</sub> Pv) is successfully synthesized on nickel foam, exhibiting a superior bifunctional hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalytic activity for seawater electrolysis in alkaline condition. As a result, bifunctional Fe-Ni<sub>2</sub> Pv achieves the industrially required current densities of 1.0 and 3.0 A cm<sup>-2</sup> at low voltages of 1.68 and 1.73 V, respectively, for seawater splitting at 60 °C in 6.0 m KOH circumstances. The theoretical calculation and the experimental results collectively reveal the reasons for the enhancement of catalyst activity. Specifically, Fe doping and P vacancies can accelerate the reconstruction of OER active species and optimize the hydrogen adsorption free energy (ΔG<sub>H*</sub> ) for HER. In addition, the active sites of Fe-Ni<sub>2</sub> Pv are identified, where P vacancies greatly improve the electrical conductivity and Ni sites are the dominant OER active centers, meanwhile Fe atoms as active centers for the HER. The study provides a deep insight into the exploration for the enhancement of activity of nickel-based phosphide catalysts and the identification of their real active centers.