Polarization-Resolved Near-Infrared PdSe<sub>2</sub> p-i-n Homojunction Photodetector.

Jiang, Jiayang; Xu, Weiting; Guo, Fuqiang; Yang, Shengxue; Ge, Weikun; Shen, Bo; Tang, Ning · Nano Lett · 2023

basic_science · Level V

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Abstract

Constructing high-quality homojunctions plays a pivotal role for the advancement of two-dimensional transition metal sulfide (TMDC) based optoelectronic devices. Here, a lateral PdSe<sub>2</sub> p-i-n homojunction is constructed by electrostatic doping. Electrical measurements reveal that the homojunction diode exhibits a strong rectifying characteristic with a rectification ratio exceeding 10<sup>4</sup> and an ideality factor approaching 1. When functioning in photovoltaic mode, the device achieves a high responsivity of 1.1 A/W under 1064 nm illumination, with a specific detectivity of 1.3 × 10<sup>11</sup> Jones and a high linearity of 45 dB. Benefiting from the lateral p-i-n structure, the junction capacitance is significantly reduced, and an ultrafast response (3/6 μs) is obtained. Additionally, the photodiode has the capability of polarization distinction due to the unique in-plane anisotropic structure of PdSe<sub>2</sub>, exhibiting a dichroic ratio of 1.6 at a 1064 nm wavelength. This high-performance polarization-sensitive near-infrared photodetector exhibits great potential in the next-generation optoelectronic applications.