Non-volatile electrical polarization switching via domain wall release in 3R-MoS<sub>2</sub> bilayer.

Yang, Dongyang; Liang, Jing; Wu, Jingda; Xiao, Yunhuan; Dadap, Jerry I; Watanabe, Kenji; Taniguchi, Takashi; Ye, Ziliang · Nat Commun · 2024

basic_science · Level V

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Abstract

Understanding the nature of sliding ferroelectricity is of fundamental importance for the discovery and application of two-dimensional ferroelectric materials. In this work, we investigate the phenomenon of switchable polarization in a bilayer MoS<sub>2</sub> with natural rhombohedral stacking, where the spontaneous polarization is coupled with excitonic effects through asymmetric interlayer coupling. Using optical spectroscopy and imaging techniques, we observe how a released domain wall switches the polarization of a large single domain. Our results highlight the importance of domain walls in the polarization switching of non-twisted rhombohedral transition metal dichalcogenides and open new opportunities for the non-volatile control of their optical response.