Thermokinetic relations.

Abstract

Thermokinetic relations bound thermodynamic quantities, such as entropy production of a physical system over a certain time interval, with statistics of kinetic (or dynamical) observables, such as mean total variation of the observable over the time interval. We introduce a thermokinetic relation to bound the entropy production or the nonadiabatic (or excess) entropy production for overdamped Markov jump processes, possibly with time-varying rates and nonstationary distributions. For stationary cases, this bound is akin to a thermodynamic uncertainty relation, only involving absolute fluctuations rather than the mean square, thereby offering a better lower bound far from equilibrium. For nonstationary cases, this bound generalizes (classical) speed limits, where the kinetic term is not necessarily the activity (number of jumps) but any trajectory observable of interest. As a consequence, in the task of driving a system from a given probability distribution to another, we find a tradeoff between nonadiabatic entropy production and housekeeping entropy production: the latter can be increased to decrease the former, although to a limited extent. We also find constraints specific to constant-rate Markov processes. We illustrate our thermokinetic relations on simple examples from biophysics and computing devices.